Rhodium

Rhodium-Catalyzed Hydroformylation of Internal Alkynes to α,β-Unsaturated Aldehydes

J. R. Johnson, Cuny, G. D. , and Buchwald, S. L. “Rhodium-Catalyzed Hydroformylation of Internal Alkynes to α,β-Unsaturated Aldehydes”, Angew. Chem. Int. Ed., 1995, 34(16), 1760-1761.

Regioselective Olefin Hydroformylation as a Route to Indolizidine and Pyrrolizidine Alkaloids

G. D. Cuny and Buchwald, S. L. “Regioselective Olefin Hydroformylation as a Route to Indolizidine and Pyrrolizidine Alkaloids”, Synlett, 1995, 1995(5), 519-522.

Practical, high-yield, regioselective, rhodium-catalyzed hydroformylation of functionalized .alpha.-olefins

G. D. Cuny and Buchwald, S. L. “Practical, high-yield, regioselective, rhodium-catalyzed hydroformylation of functionalized .alpha.-olefins”, J. Am. Chem. Soc., 1993, 115(5), 2066-2068.

Enantioselective β-arylation of ketones enabled by lithiation/borylation/1,4-addition sequence under flow conditions

W. Shu and Buchwald, S. L. “Enantioselective β-arylation of ketones enabled by lithiation/borylation/1,4-addition sequence under flow conditions”, Angew. Chem. Int. Ed., 2012, 51, 5355-5358.

Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins

X. Wang and Buchwald, S. L. “Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins”, J. Am. Chem. Soc., 2011, 133(47), 19080-3.

Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes

X. Shen and Buchwald, S. L. “Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes”, Angew. Chem. Int. Ed., 2010, 49, 564-7.

Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation

X. Wang and Buchwald, S. L. “Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation”, J. Org. Chem., 2013, 78(7), 3429 - 3433.