Robert B. Grossman

Lab Positions	Start Date	End Date	End Date2	Degree Received	Current Position	Previous Institutions
Graduate Student		1992	1992	PhD	Professor University of Kentucky, Lexington, KY

Development of a Titanocene-Catalyzed Enyne Cyclization/Isocyanide Insertion Reaction	Berk, S. C. ; Grossman, R. B. ; Buchwald, S. L. . J. Am. Chem. Soc. 1994, 116, 8593-8601.
Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex	Grossman, R. B. ; Tsai, J. - C. ; Davis, W. M. ; Gutierrez, A. ; Buchwald, S. L. . Organometallics 1994, 13, 3892-3896.
Titanocene-catalyzed conversion of enynes to bicyclic cyclopentenones	Berk, S. C. ; Grossman, R. B. ; Buchwald, S. L. . J. Am. Chem. Soc. 1993, 115, 4912-4913 .
Reductive cyclization of ester-containing enynes with a practical titanocene reagent. Synthesis of bicyclic cyclopentenones and iminocyclopentenes	Grossman, R. B. ; Buchwald, S. L. . J. Org. Chem. 1992, 57, 5803-5805.
Enantioselective, zirconium-mediated synthesis of allylic amines	Grossman, R. B. ; Davis, W. M. ; Buchwald, S. L. . J. Am. Chem. Soc. 1991, 113, 2321-2322.
Syntheses of [ethylene-1,2-bis(.eta.5-4,5,6,7-tetrahydro-1-indenyl)]zirconium and -hafnium hydride complexes. Improved syntheses of the corresponding dichlorides	Grossman, R. B. ; Doyle, R. Ann; Buchwald, S. L. . Organometallics 1991, 10, 1501-1505.

Catalytic Asymmetric Reduction of Ketones Using Metal Catalysts.	Buchwald, S.L.; Gutiérrez, A.; Grossman, R.B.	U.S. Patent No. 5,227,538	July 13, 1993
Preparation of Chiral Metallocene Dihalides.	Buchwald, S.L.; Grossman, R.B.	U.S. Patent No. 5,004,820	April 2, 1991

The Buchwald Research Group