Timothy E. Barder | The Buchwald Research Group

Lab Positions	Start Date	End Date	End Date2	Degree Received	Current Position	Previous Institutions
Graduate Student		2007	2007	PhD	Consultant Arthur D. Little, Boston, MA

Palladium-Catalyzed Carbonylation Reactions of Aryl Bromides at Atmospheric Pressure: A General System Based on Xantphos	Martinelli, J. R. ; Watson, D. A. ; Freckmann, D. M. M. ; Barder, T. E. ; Buchwald, S. L. . J. Org. Chem. 2008, 73, 7102-7107.
Electronic Effects on the Selectivity of Pd-Catalyzed C–N Bond-Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity	Biscoe, M. R. ; Barder, T. E. ; Buchwald, S. L. . Angew. Chem. Int. Ed. 2007, 46, 7232-7235.
Pd-Catalyzed Amidations of Aryl Chlorides Using Monodentate Biaryl Phosphine Ligands: A Kinetic, Computational, and Synthetic Investigation	Ikawa, T. ; Barder, T. E. ; Biscoe, M. R. ; Buchwald, S. L. . J. Am. Chem. Soc. 2007, 129, 13001-13007.
Palladium-Catalyzed Silylation of Aryl Chlorides with Hexamethyldisilane	McNeill, E. ; Barder, T. E. ; Buchwald, S. L. . Org. Lett. 2007, 9, 3785-3788.
Palladium-Catalyzed Borylation of Aryl Chlorides: Scope, Applications, and Computational Studies	Billingsley, K. L. ; Barder, T. E. ; Buchwald, S. L. . Angew. Chem. Int. Ed. 2007, 46, 5359-5363.
Structural Insights into Active Catalyst Structures and Oxidative Addition to (Biaryl)phosphine−Palladium Complexes via Density Functional Theory and Experimental Studies	Barder, T. E. ; Biscoe, M. R. ; Buchwald, S. L. . Organometallics 2007, 26, 2183-2192.
Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen	Barder, T. E. ; Buchwald, S. L. . J. Am. Chem. Soc. 2007, 129, 5096-5101.
Insights into Amine Binding to Biaryl Phosphine Palladium Oxidative Addition Complexes and Reductive Elimination from Biaryl Phosphine Arylpalladium Amido Complexes via Density Functional Theory	Barder, T. E. ; Buchwald, S. L. . J. Am. Chem. Soc. 2007, 129, 12003-12010.
Benchtop Monitoring of Reaction Progress via Visual Recognition with a Handheld UV Lamp: In Situ Monitoring of Boronic Acids in the Suzuki−Miyaura Reaction	Barder, T. E. ; Buchwald, S. L. . Org. Lett. 2007, 9, 137-139.
Significantly Improved Method for the Pd-Catalyzed Coupling of Phenols with Aryl Halides: Understanding Ligand Effects	Burgos, C. H. ; Barder, T. E. ; Huang, X. ; Buchwald, S. L. . Angew. Chem. Int. Ed. 2006, 45, 4321-4326.
New Insights into Xantphos/Pd-Catalyzed C−N Bond Forming Reactions: A Structural and Kinetic Study	Klingensmith, L. M. ; Strieter, E. R. ; Barder, T. E. ; Buchwald, S. L. . Organometallics 2006, 25, 82-91.
Catalysts for Suzuki−Miyaura Coupling Processes: Scope and Studies of the Effect of Ligand Structure	Barder, T. E. ; Walker, S. D. ; Martinelli, J. R. ; Buchwald, S. L. . J. Am. Chem. Soc. 2005, 127, 4685-4696.
Copper−Diamine-Catalyzed N-Arylation of Pyrroles, Pyrazoles, Indazoles, Imidazoles, and Triazoles	Antilla, J. C. ; Baskin, J. M. ; Barder, T. E. ; Buchwald, S. L. . J. Org. Chem. 2004, 69, 5578-5587.
Efficient Catalyst for the Suzuki−Miyaura Coupling of Potassium Aryl Trifluoroborates with Aryl Chlorides	Barder, T. E. ; Buchwald, S. L. . Org. Lett. 2004, 6, 2649-2652.
A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes	Walker, S. D. ; Barder, T. E. ; Martinelli, J. R. ; Buchwald, S. L. . Angew. Chem. Int. Ed. 2004, 43, 1871-1876.

Publications