Zim, Danilo
Buchwald, Stephen L.

An Air and Thermally Stable One- Component Catalyst for the Amination of Aryl Chlorides

“,
Org. Lett.
,
2003
,
5
(
14
)
,
2413-2415
.
Abstract

In this paper we report a new, highly efficient palladacyclic precatalyst that is air, moisture, and thermally stable and obviates the need to employ a glovebox. We have developed a convenient one-component precatalyst for the amination of aryl chlorides that overcomes many of the limitations of those previously described.