Hsu, Donald P.
A. Lucas, Eric
Buchwald, Stephen L.

Synthesis and reactions of a zirconocene-benzdiyne equivalent

“,
Tet. Lett.
,
1990
,
31
(
39
)
,
5563-5566
.
Abstract

The zirconocene complex of 3-methoxy-4-[(methyl)zirconocene]banzyne, 1, has been prepared and isolated as its trimethylphosphine adduct. In addition, the reaction of 1 with a variety of unsaturated organic molecules has been investigated. In these reactions, 1 serves as the synthetic equivalent of the bis(zirconocene)3-mathoxybenzdiyne complex.