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Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations |
Shen, X. ; Jones, G. O. ; Watson, D. A. ; Bhayana, B. ; Buchwald, S. L. . J. Am. Chem. Soc. 2010, 132, 11278-11287. |
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The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides |
Cho, E. J. ; Senecal, T. D. ; Kinzel, T. ; Zhang, Y. ; Watson, D. A. ; Buchwald, S. L. . Science 2010, 328, 1679-1681. |
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Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides |
Watson, D. A. ; Su, M. ; Teverovskiy, G. ; Zhang, Y. ; Garcia-Fortanet, J. ; Kinzel, T. ; Buchwald, S. L. . Science 2009, 325, 1661-1664. |
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A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides |
Fors, B. P. ; Watson, D. A. ; Biscoe, M. R. ; Buchwald, S. L. . J. Am. Chem. Soc. 2008, 130, 13552-13554. |
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Palladium-Catalyzed Carbonylation Reactions of Aryl Bromides at Atmospheric Pressure: A General System Based on Xantphos |
Martinelli, J. R. ; Watson, D. A. ; Freckmann, D. M. M. ; Barder, T. E. ; Buchwald, S. L. . J. Org. Chem. 2008, 73, 7102-7107. |
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Carbonylation of Aryl Chlorides with Oxygen Nucleophiles at Atmospheric Pressure. Preparation of Phenyl Esters as Acyl Transfer Agents and the Direct Preparation of Alkyl Esters and Carboxylic Acids |
Watson, D. A. ; Fan, X. ; Buchwald, S. L. . J. Org. Chem. 2008, 73, 7096-7101. |
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Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide |
Martinelli, J. R. ; Clark, T. P. ; Watson, D. A. ; Munday, R. H. ; Buchwald, S. L. . Angew. Chem. Int. Ed. 2007, 46, 8460-8463. |
