2009

Patent: Ligands for transition-metal-catalyzed cross-couplings, and methods of use thereof.

Patent: Transition-metal-catalyzed carbon-nitrogen and carbon-carbon bond-forming reactions.

Patent: Ligands for Metals and Improved Metal-Catalyzed Processes Based Thereon.

A Versatile Catalyst System for Suzuki−Miyaura Cross-Coupling Reactions of C(sp2)-Tosylates and Mesylates

B. Bhayana, Fors, B. P. , and Buchwald, S. L. “A Versatile Catalyst System for Suzuki−Miyaura Cross-Coupling Reactions of C(sp2)-Tosylates and Mesylates”, Org. Lett., 2009, 11(17), 3954-3957.

Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides

M. R. Biscoe and Buchwald, S. L. “Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides”, Org. Lett., 2009, 11(8), 1773-1775.

On the Role of Metal Contaminants in Catalyses with FeCl3

S. L. Buchwald and Bolm, C. “On the Role of Metal Contaminants in Catalyses with FeCl3”, Angew. Chem. Int. Ed., 2009, 48(31), 5586-5587.

Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics

B. P. Fors and Buchwald, S. L. “Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics”, J. Am. Chem. Soc., 2009, 131(36), 12898-12899.

An Efficient Process for Pd-Catalyzed C−N Cross-Coupling Reactions of Aryl Iodides: Insight Into Controlling Factors

B. P. Fors, Davis, N. R. , and Buchwald, S. L. “An Efficient Process for Pd-Catalyzed C−N Cross-Coupling Reactions of Aryl Iodides: Insight Into Controlling Factors”, J. Am. Chem. Soc., 2009, 131(16), 5766-5768.

An efficient system for the Pd-catalyzed cross-coupling of amides and aryl chlorides

B. P. Fors, Dooleweerdt, K. , Zeng, Q. , and Buchwald, S. L. “An efficient system for the Pd-catalyzed cross-coupling of amides and aryl chlorides”, Tetrahedron, 2009, 65(33), 6576-6583.

Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives

J. García-Fortanet, Kessler, F. , and Buchwald, S. L. “Palladium-Catalyzed Asymmetric Dearomatization of Naphthalene Derivatives”, J. Am. Chem. Soc., 2009, 131(19), 6676-6677.

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