2013

An Improved Catalyst System for the Pd-Catalyzed Fluorination of (Hetero)Aryl Triflates

H. Geun Lee, Milner, P. J. , and Buchwald, S. L. “An Improved Catalyst System for the Pd-Catalyzed Fluorination of (Hetero)Aryl Triflates”, Org. Lett., 2013, 15(21), 5602 - 5605.

Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst

C. Wai Cheung and Buchwald, S. L. “Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst”, Org. Lett., 2013, 15(15), 3998 - 4001.

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts

C. Wai Cheung, Surry, D. S. , and Buchwald, S. L. “Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts”, Org. Lett., 2013, 15(14), 3734 - 3737.

Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands

N. C. Bruno and Buchwald, S. L. “Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands”, Org. Lett., 2013, 15(11), 2876 - 2879.

Palladium-Catalyzed Synthesis of N-Aryl Carbamates

E. V. Vinogradova, Park, N. H. , Fors, B. P. , and Buchwald, S. L. “Palladium-Catalyzed Synthesis of N-Aryl Carbamates”, Org. Lett., 2013, 15(6), 1394 - 1397.

Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation

X. Wang and Buchwald, S. L. “Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation”, J. Org. Chem., 2013, 78(7), 3429 - 3433.

Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes

S. Zhu, Niljianskul, N. , and Buchwald, S. L. “Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes”, J. Am. Chem. Soc., 2013, 135(42), 15746 - 15749.

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

A. M. Düfert, Billingsley, K. L. , and Buchwald, S. L. “Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation”, J. Am. Chem. Soc., 2013, 135(34), 12877 - 12885.

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

Y. Yang and Buchwald, S. L. “Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides”, J. Am. Chem. Soc., 2013, 135(29), 10642 - 10645.

Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids

R. J. DeBergh, Niljianskul, N. , and Buchwald, S. L. “Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids”, J. Am. Chem. Soc., 2013, 135(29), 10638 - 10641.

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