2015

Enantioselective Synthesis of α-Aminosilanes by Copper-Catalyzed Hydroamination of Vinylsilanes

N. Niljianskul, Zhu, S. , and Buchwald, S. L. “Enantioselective Synthesis of α-Aminosilanes by Copper-Catalyzed Hydroamination of Vinylsilanes”, Angew. Chem. Int. Ed., 2015, 54(5), 1638 - 1641.

In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides

P. J. Milner, Yang, Y. , and Buchwald, S. L. “In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides”, Organometallics, 2015, 34(19), 4775–4780.

Dosage delivery of sensitive reagents enables glove-box-free synthesis

A. C. Sather, Lee, H. Geun, Colombe, J. R. , Zhang, A. , and Buchwald, S. L. “Dosage delivery of sensitive reagents enables glove-box-free synthesis”, Nature, 2015, 524(7564), 208 - 211.

Enantioselective Synthesis of Carbo- and Heterocycles Through a CuH-Catalyzed Hydroalkylation Approach

Y. - M. Wang, Bruno, N. C. , Placeres, Á. L. , Zhu, S. , and Buchwald, S. L. “Enantioselective Synthesis of Carbo- and Heterocycles Through a CuH-Catalyzed Hydroalkylation Approach”, J. Am. Chem. Soc., 2015, 137(33), 10524–10527.

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination

D. Niu and Buchwald, S. L. “Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination”, J. Am. Chem. Soc., 2015, 137(30), 9716.

Stig Friis

Haoxuan Wang

Mycah Uehling

Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines

N. H. Park, Vinogradova, E. V. , Surry, D. S. , and Buchwald, S. L. “Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines”, Angew. Chem. Int. Ed., 2015, 54(28), 8259 - 8262.

Synthesis of Heteroaryl Sulfonamides from Organozinc Reagents and 2,4,6-Trichlorophenyl Chlorosulfate

J. R. Colombe, J. DeBergh, R. , and Buchwald, S. L. “Synthesis of Heteroaryl Sulfonamides from Organozinc Reagents and 2,4,6-Trichlorophenyl Chlorosulfate”, Org. Lett., 2015, 17(12), 3170 - 3173.

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