C—O

Palladium-Catalyzed Intramolecular C−O Bond Formation

S. - I. Kuwabe, Torraca, K. E. , and Buchwald, S. L. “Palladium-Catalyzed Intramolecular C−O Bond Formation”, J. Am. Chem. Soc., 2001, 123(49), 12202-12206.

A High-Yield, General Method for the Catalytic Formation of Oxygen Heterocycles

K. E. Torraca, Kuwabe, S. - I. , and Buchwald, S. L. “A High-Yield, General Method for the Catalytic Formation of Oxygen Heterocycles”, J. Am. Chem. Soc., 2000, 122(51), 12907-12908.

Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers

A. Aranyos, Old, D. W. , Kiyomori, A. , Wolfe, J. P. , Sadighi, J. P. , and Buchwald, S. L. “Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers”, J. Am. Chem. Soc., 1999, 121(18), 4369-4378.

On the Role of Metal Contaminants in Catalyses with FeCl3

S. L. Buchwald and Bolm, C. “On the Role of Metal Contaminants in Catalyses with FeCl3”, Angew. Chem. Int. Ed., 2009, 48(31), 5586-5587.

Orthogonal Cu- and Pd-Based Catalyst Systems for the O- and N-Arylation of Aminophenols

D. Maiti and Buchwald, S. L. “Orthogonal Cu- and Pd-Based Catalyst Systems for the O- and N-Arylation of Aminophenols”, J. Am. Chem. Soc., 2009, 131(47), 17423-17429.

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions

G. O. Jones, Liu, P. , Houk, K. N. , and Buchwald, S. L. “Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions”, J. Am. Chem. Soc., 2010, 132(17), 6205-6213.

Pd-Catalyzed O-Arylation of Ethyl Acetohydroximate: Synthesis of O-Arylhydroxylamines and Substituted Benzofurans

T. J. Maimone and Buchwald, S. L. “Pd-Catalyzed O-Arylation of Ethyl Acetohydroximate: Synthesis of O-Arylhydroxylamines and Substituted Benzofurans”, J. Am. Chem. Soc., 2010, 132(29), 9990-9991.

Cu-Catalyzed Arylation of Phenols: Synthesis of Sterically Hindered and Heteroaryl Diaryl Ethers

D. Maiti and Buchwald, S. L. “Cu-Catalyzed Arylation of Phenols: Synthesis of Sterically Hindered and Heteroaryl Diaryl Ethers”, J. Org. Chem., 2010, 75(5), 1791-1794.

Me3(OMe)tBuXPhos: a surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions

S. Ueda, Ali, S. , Fors, B. P. , and Buchwald, S. L. “Me3(OMe)tBuXPhos: a surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions”, J. Org. Chem., 2012, 77(5), 2543-7.

Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst

C. Wai Cheung and Buchwald, S. L. “Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst”, Org. Lett., 2013, 15(15), 3998 - 4001.

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