2006

Erica Koval

Patent: Copper-catalyzed Formation of Carbon-heteroatom and Carbon-carbon bonds.

Patent: Protecting Groups Useful in the Synthesis of Polysaccharides, Natural Products, and Combinatorial Libraries

Patent: Stereoisomers of p-hydroxy-milnacipran, and Methods of Use Thereof

Patent: Ligands for Metals and Improved Metal-catalyzed Processes Based Thereon.

Expedited Palladium-Catalyzed Amination of Aryl Nonaflates through the Use of Microwave-Irradiation and Soluble Organic Amine Bases

R. E. Tundel, Anderson, K. W. , and Buchwald, S. L. “Expedited Palladium-Catalyzed Amination of Aryl Nonaflates through the Use of Microwave-Irradiation and Soluble Organic Amine Bases”, J. Org. Chem., 2006, 71(1), 430-433.

Evidence for the Formation and Structure of Palladacycles during Pd-Catalyzed C–N Bond Formation with Catalysts Derived from Bulky Monophosphinobiaryl Ligands

E. R. Strieter and Buchwald, S. L. “Evidence for the Formation and Structure of Palladacycles during Pd-Catalyzed C–N Bond Formation with Catalysts Derived from Bulky Monophosphinobiaryl Ligands”, Angew. Chem. Int. Ed., 2006, 45(6), 925-928.

Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes

S. Shekhar, Ryberg, P. , Hartwig, J. F. , Mathew, J. S. , Blackmond, D. G. , Strieter, E. R. , and Buchwald, S. L. “Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes”, J. Am. Chem. Soc., 2006, 128(11), 3584-3591.

Highly Selective Room-Temperature Copper-Catalyzed C−N Coupling Reactions

A. Shafir and Buchwald, S. L. “Highly Selective Room-Temperature Copper-Catalyzed C−N Coupling Reactions”, J. Am. Chem. Soc., 2006, 128(27), 8742-8743.

Convenient Method for the Preparation of Weinreb Amides via Pd-Catalyzed Aminocarbonylation of Aryl Bromides at Atmospheric Pressure

J. R. Martinelli, Freckmann, D. M. M. , and Buchwald, S. L. “Convenient Method for the Preparation of Weinreb Amides via Pd-Catalyzed Aminocarbonylation of Aryl Bromides at Atmospheric Pressure”, Org. Lett., 2006, 8(21), 4843-4846.

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