2007

Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide

J. R. Martinelli, Clark, T. P. , Watson, D. A. , Munday, R. H. , and Buchwald, S. L. “Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides at Atmospheric Pressure: The Dual Role of Sodium Phenoxide”, Angew. Chem. Int. Ed., 2007, 46(44), 8460-8463.

Cu-Catalyzed Tandem C−N Bond Formation for the Synthesis of Pyrroles and Heteroarylpyrroles

R. Martín, Larsen, C. H. , Cuenca, A. , and Buchwald, S. L. “Cu-Catalyzed Tandem C−N Bond Formation for the Synthesis of Pyrroles and Heteroarylpyrroles”, Org. Lett., 2007, 9(17), 3379-3382.

Sequential Copper-Catalyzed Vinylation/Cyclization: An Efficient Synthesis of Functionalized Oxazoles

R. Martín, Cuenca, A. , and Buchwald, S. L. “Sequential Copper-Catalyzed Vinylation/Cyclization: An Efficient Synthesis of Functionalized Oxazoles”, Org. Lett., 2007, 9(26), 5521-5524.

A General Method for the Direct α-Arylation of Aldehydes with Aryl Bromides and Chlorides

R. Martín and Buchwald, S. L. “A General Method for the Direct α-Arylation of Aldehydes with Aryl Bromides and Chlorides”, Angew. Chem. Int. Ed., 2007, 46(38), 7236-7239.

Pd-Catalyzed Kumada−Corriu Cross-Coupling Reactions at Low Temperatures Allow the Use of Knochel-type Grignard Reagents

R. Martín and Buchwald, S. L. “Pd-Catalyzed Kumada−Corriu Cross-Coupling Reactions at Low Temperatures Allow the Use of Knochel-type Grignard Reagents”, J. Am. Chem. Soc., 2007, 129(13), 3844-3845.

Sequential Cu-Catalyzed Amidation-Base-Mediated Camps Cyclization: A Two-Step Synthesis of 2-Aryl-4-quinolones fromo-Halophenones

C. P. Jones, Anderson, K. W. , and Buchwald, S. L. “Sequential Cu-Catalyzed Amidation-Base-Mediated Camps Cyclization: A Two-Step Synthesis of 2-Aryl-4-quinolones fromo-Halophenones”, J. Org. Chem., 2007, 72(21), 7968-7973.

Pd-Catalyzed Amidations of Aryl Chlorides Using Monodentate Biaryl Phosphine Ligands: A Kinetic, Computational, and Synthetic Investigation

T. Ikawa, Barder, T. E. , Biscoe, M. R. , and Buchwald, S. L. “Pd-Catalyzed Amidations of Aryl Chlorides Using Monodentate Biaryl Phosphine Ligands: A Kinetic, Computational, and Synthetic Investigation”, J. Am. Chem. Soc., 2007, 129(43), 13001-13007.

Electronic Effects on the Selectivity of Pd-Catalyzed C–N Bond-Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity

M. R. Biscoe, Barder, T. E. , and Buchwald, S. L. “Electronic Effects on the Selectivity of Pd-Catalyzed C–N Bond-Forming Reactions Using Biarylphosphine Ligands: The Competitive Roles of Amine Binding and Acidity”, Angew. Chem. Int. Ed., 2007, 46(38), 7232-7235.

Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki−Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters

K. Billingsley and Buchwald, S. L. “Highly Efficient Monophosphine-Based Catalyst for the Palladium-Catalyzed Suzuki−Miyaura Reaction of Heteroaryl Halides and Heteroaryl Boronic Acids and Esters”, J. Am. Chem. Soc., 2007, 129(11), 3358-3366.

Benchtop Monitoring of Reaction Progress via Visual Recognition with a Handheld UV Lamp: In Situ Monitoring of Boronic Acids in the Suzuki−Miyaura Reaction

T. E. Barder and Buchwald, S. L. “Benchtop Monitoring of Reaction Progress via Visual Recognition with a Handheld UV Lamp: In Situ Monitoring of Boronic Acids in the Suzuki−Miyaura Reaction”, Org. Lett., 2007, 9(1), 137-139.

Pages