Mechanistic Studies

Papers describing mechanistic studies.

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations

X. Shen, Jones, G. O. , Watson, D. A. , Bhayana, B. , and Buchwald, S. L. “Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations”, J. Am. Chem. Soc., 2010, 132(32), 11278-11287.

Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes

P. J. Milner, Maimone, T. J. , Su, M. , Müller, P. , and Buchwald, S. L. “Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes”, J. Am. Chem. Soc., 2012, 134(48), 19922 - 19934.

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

A. M. Düfert, Billingsley, K. L. , and Buchwald, S. L. “Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation”, J. Am. Chem. Soc., 2013, 135(34), 12877 - 12885.

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