Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex
“Synthesis and Structure of a C2-Symmetric, Doubly Bridged ansa-Titanocene Complex”, Organometallics, 1994, 13(10), 3892-3896.
Abstract:
A chiral, doubly bridged ansa-titanocene complex with C2 symmetry has been synthesized in four steps from bicyclo[3.3.1]nonane-2,6-dione. The design of the complex precludes the formation of meso or C1 diastereomers or conformers.