Copper

Copper-catalyzed reactions.

On the Role of Metal Contaminants in Catalyses with FeCl3

S. L. Buchwald and Bolm, C. “On the Role of Metal Contaminants in Catalyses with FeCl3”, Angew. Chem. Int. Ed., 2009, 48(31), 5586-5587.

Orthogonal Cu- and Pd-Based Catalyst Systems for the O- and N-Arylation of Aminophenols

D. Maiti and Buchwald, S. L. “Orthogonal Cu- and Pd-Based Catalyst Systems for the O- and N-Arylation of Aminophenols”, J. Am. Chem. Soc., 2009, 131(47), 17423-17429.

Mechanistic Studies on the Copper-Catalyzed N-Arylation of Amides

E. R. Strieter, Bhayana, B. , and Buchwald, S. L. “Mechanistic Studies on the Copper-Catalyzed N-Arylation of Amides”, J. Am. Chem. Soc., 2009, 131(1), 78-88.

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions

G. O. Jones, Liu, P. , Houk, K. N. , and Buchwald, S. L. “Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions”, J. Am. Chem. Soc., 2010, 132(17), 6205-6213.

Cu-Catalyzed Arylation of Phenols: Synthesis of Sterically Hindered and Heteroaryl Diaryl Ethers

D. Maiti and Buchwald, S. L. “Cu-Catalyzed Arylation of Phenols: Synthesis of Sterically Hindered and Heteroaryl Diaryl Ethers”, J. Org. Chem., 2010, 75(5), 1791-1794.

Diamine Ligands in Copper-Catalyzed Reactions

D. S. Surry and Buchwald, S. L. “Diamine Ligands in Copper-Catalyzed Reactions”, Chem. Sci., 2010, 1(1), 13-31.

Copper-catalysed Selective Hydroamination Reactions of Alkynes

S. - L. Shi and Buchwald, S. L. “Copper-catalysed Selective Hydroamination Reactions of Alkynes”, Nat. Chem., 2015, 7(1), 38 - 44.

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes

S. Zhu and Buchwald, S. L. “Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes”, J. Am. Chem. Soc., 2014, 136(45), 15913 - 15916.

Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes

S. Zhu, Niljianskul, N. , and Buchwald, S. L. “Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes”, J. Am. Chem. Soc., 2013, 135(42), 15746 - 15749.

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

R. Zhu and Buchwald, S. L. “Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes”, Angew. Chem. Int. Ed., 2013, 52(48), 12655 - 12658.

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