Copper

Copper-catalyzed reactions.

Copper-Catalyzed Regioselective ortho C–H Cyanation of Vinylarenes

Y. Yang and Buchwald, S. L. “Copper-Catalyzed Regioselective ortho C–H Cyanation of Vinylarenes”, Angew. Chem. Int. Ed., 2014, 53(33), 8677 - 8681.

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

R. Zhu and Buchwald, S. L. “Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes”, J. Am. Chem. Soc., 2015, 137(25), 8069 - 8077.

Catalytic Asymmetric Hydroamination of Unactivated Internal Olefins to Aliphatic Amines

Y. Yang, Shi, S. - L. , Niu, D. , Liu, P. , and Buchwald, S. L. “Catalytic Asymmetric Hydroamination of Unactivated Internal Olefins to Aliphatic Amines”, Science, 2015, 349(6243), 62 - 66.

A general copper-catalyzed synthesis of diaryl ethers

J. F. Marcoux, Doye, S. , and Buchwald, S. L. “A general copper-catalyzed synthesis of diaryl ethers”, J. Am. Chem. Soc., 1997, 119(43), 10539-10540.

Rapid and Efficient Copper-Catalyzed Finkelstein Reaction of (Hetero)Aromatics under Continuous-Flow Conditions

M. Chen, Ichikawa, S. , and Buchwald, S. L. “Rapid and Efficient Copper-Catalyzed Finkelstein Reaction of (Hetero)Aromatics under Continuous-Flow Conditions”, Angew. Chem. Int. Ed., 2014, 54, 263-266.

Copper-catalyzed oxytrifluoromethylation of unactivated alkenes

R. Zhu and Buchwald, S. L. “Copper-catalyzed oxytrifluoromethylation of unactivated alkenes”, J. Am. Chem. Soc., 2012, 134(30), 12462-12465.

Room temperature copper(II)-catalyzed oxidative cyclization of enamides to 2,5-disubstituted oxazoles via vinylic C-H functionalization

C. W. Cheung and Buchwald, S. L. “Room temperature copper(II)-catalyzed oxidative cyclization of enamides to 2,5-disubstituted oxazoles via vinylic C-H functionalization”, J. Org. Chem., 2012, 77, 7526-37.

Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling

T. D. Senecal, Parsons, A. T. , and Buchwald, S. L. “Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling”, J. Org. Chem., 2011, 76(4), 1174-1176.

Copper-catalyzed trifluoromethylation of unactivated olefins

A. T. Parsons and Buchwald, S. L. “Copper-catalyzed trifluoromethylation of unactivated olefins”, Angew. Chem. Int. Ed., 2011, 50(39), 9120-3.

Commentary on "A New, Efficient and Recyclable Lanthanum(III) Oxide-Catalyzed C-N Cross-Coupling" by S. Narayana Murthy, B. Madhav, V. Prakash Reddy, and Y. V. D. Nageswar, Adv. Synth. Catal. 2010, 352, 3241-3245

B. P. Fors and Buchwald, S. L. “Commentary on "A New, Efficient and Recyclable Lanthanum(III) Oxide-Catalyzed C-N Cross-Coupling" by S. Narayana Murthy, B. Madhav, V. Prakash Reddy, and Y. V. D. Nageswar, Adv. Synth. Catal. 2010, 352, 3241-3245”, Adv. Synth. Catal., 2010, 352, 3119-3120.

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