Copper

Copper-catalyzed reactions.

Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

G. Lu, Liu, R. Y. , Yang, Y. , Fang, C. , Lambrecht, D. S. , Buchwald, S. L. , and Liu, P. “Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins”, J. Am. Chem. Soc, 2017, 139(46), 16548–16555.

CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines

H. Wang, Yang, J. Chih- Yeh, and Buchwald, S. L. “CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines”, J. Am. Chem. Soc, 2017, 139, 8428-8431.

Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates

Y. Zhou, Bandar, J. S. , and Buchwald, S. L. “Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates”, J. Am. Chem. Soc, 2017, 139(24), 8126–8129.

A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl–Aryl Cross-Coupling of Aryl Halides and Olefins

S. D. Friis, Pirnot, M. T. , Dupuis, L. N. , and Buchwald, S. L. “A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl–Aryl Cross-Coupling of Aryl Halides and Olefins”, Angew. Chem. Int. Ed., 2017, 56(25), 7242–7246 .

Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles

M. W. Gribble, Pirnot, M. T. , Bandar, J. S. , Liu, R. Y. , and Buchwald, S. L. “Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles”, J. Am. Chem. Soc, 2017, 139(6), 2192-2195.

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes

R. Y. Liu, Yang, Y. , and Buchwald, S. L. “Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes”, Angew. Chem. Int. Ed., 2016, 55(45), 14077-14080.

Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration

Y. Yang, Perry, I. B. , and Buchwald, S. L. “Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration”, J. Am. Chem. Soc., 2016, 138(31), 9787-9790.

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis

S. D. Friis, Pirnot, M. T. , and Buchwald, S. L. “Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis”, J. Am. Chem. Soc., 2016, 138, 8372-8375.

Copper-Catalyzed Asymmetric Addition of Olefin-Derived Nucleophiles to Ketones

Y. Yang, Perry, I. B. , Lu, G. , Liu, P. , and Buchwald, S. L. “Copper-Catalyzed Asymmetric Addition of Olefin-Derived Nucleophiles to Ketones”, Science, 2016, 353(6295), 144-150.

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids

J. S. Bandar, Ascic, E. , and Buchwald, S. L. “Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids”, J. Am. Chem. Soc., 2016, 138, 5821-5824.

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