Copper

Copper-catalyzed reactions.

Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles

Y. Zhou, Zhou, L. , Jesikiewicz, L. T. , Liu, P. , and Buchwald, S. L. “Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles”, J. Am. Chem. Soc., 2020, 142(22), 9908-9914.

Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes

S. Feng, Hao, H. , Liu, P. , and Buchwald, S. L. “Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes”, ACS Catal, 2020, 10, 282-291.

Enantioselective Olefin Hydrocyanation Without Cyanide

A. W. Schuppe, Borrajo-Calleja, G. M. , and Buchwald, S. L. “Enantioselective Olefin Hydrocyanation Without Cyanide”, J. Am. Chem. Soc., 2019, 141, 18668-18672.

Asymmetric Synthesis of γ-Amino Alcohols by Copper-Catalyzed Hydroamination

S. Ichikawa and Buchwald, S. L. “Asymmetric Synthesis of γ-Amino Alcohols by Copper-Catalyzed Hydroamination”, Organic Letters, 2019, 21, 8736-8739.

Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles

C. Li*, Shin*, K. , Y.Liu, R. , and Buchwald, S. L. “Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles”, Angew. Chem. Int. Ed., 2019, 58, 17074-17080.

Copper Hydride-Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes

L. Bayeh-Romero and Buchwald, S. L. “Copper Hydride-Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes”, J. Am. Chem. Soc., 2019, 2019(141), 13788-13794.

Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination

S. Ichikawa, Dai, X. - J. , and Buchwald, S. L. “Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination”, Org. Lett. , 2019, 21(11), 4370-4373.

CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications

C. Li, Liu, R. Y. , Jesikiewicz, L. T. , Yang, Y. , Liu, P. , and Buchwald, S. L. “CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications”, J. Am. Chem. Soc., 2019, 141(12), 5062-5070.

CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence

Y. Ye, Kim, S. - T. , Jeong, J. , Baik, M. - H. , and Buchwald, S. L. “CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence”, J. Am. Chem. Soc., 2019, 141(9), 3901-3909.

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct

R. Y. Liu, Zhou, Y. , Yang, Y. , and Buchwald, S. L. “Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct”, J. Am. Chem. Soc., 2019, 141, 2251-2256.

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