2017

Palladium-Catalyzed Negishi Coupling of α-CF3 Oxiranyl Zincate: Access to Chiral CF3-substituted Benzylic Tertiary Alcohols

H. Zhang and Buchwald, S. L. “Palladium-Catalyzed Negishi Coupling of α-CF3 Oxiranyl Zincate: Access to Chiral CF3-substituted Benzylic Tertiary Alcohols”, J. Am. Chem. Soc, 2017, 139, 11590-11594.

Mechanistic Insight Leads to a Ligand That Facilitates the Pd-Catalyzed Formation of 2-(Hetero)Arylaminooxazoles and 4-(Hetero)Arylaminothiazoles

E. P. K. Olsen, Arrechea, P. L. , and Buchwald, S. L. “Mechanistic Insight Leads to a Ligand That Facilitates the Pd-Catalyzed Formation of 2-(Hetero)Arylaminooxazoles and 4-(Hetero)Arylaminothiazoles”, Angew. Chem. Int. Ed., 2017, 56, 10569-10572.

CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines

H. Wang, Yang, J. Chih- Yeh, and Buchwald, S. L. “CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines”, J. Am. Chem. Soc, 2017, 139, 8428-8431.

Liang Zhang

Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates

Y. Zhou, Bandar, J. S. , and Buchwald, S. L. “Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates”, J. Am. Chem. Soc, 2017, 139(24), 8126–8129.

Andy Thomas

Ivan Varela Sanda

A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl–Aryl Cross-Coupling of Aryl Halides and Olefins

S. D. Friis, Pirnot, M. T. , Dupuis, L. N. , and Buchwald, S. L. “A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl–Aryl Cross-Coupling of Aryl Halides and Olefins”, Angew. Chem. Int. Ed., 2017, 56(25), 7242–7246 .

Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands

B. T. Ingoglia and Buchwald, S. L. “Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands”, Org. Lett., 2017, 19(11), 2853–2856.

Direct 11CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions

W. Zhao, Lee, H. Geun, Buchwald, S. L. , and Hooker, J. M. “Direct 11CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions”, J. Am. Chem. Soc, 2017, 139(21), 7152–7155.

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