C—C (All)

Carbon—carbon bond forming reactions.

Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides

Y. Yang, Niedermann, K. , Han, C. , and Buchwald, S. L. “Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides”, Org. Lett., 2014, 16(17), 4638 - 4641.

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst

S. D. Friis, Skrydstrup, T. , and Buchwald, S. L. “Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst”, Org. Lett., 2014, 16(16), 4296 - 4299.

Synthesis of Solid 2-Pyridylzinc Reagents and Their Application in Negishi Reactions

J. R. Colombe, Bernhardt, S. , Stathakis, C. , Buchwald, S. L. , and Knochel, P. “Synthesis of Solid 2-Pyridylzinc Reagents and Their Application in Negishi Reactions”, Org. Lett., 2013, 15(22), 5754 - 5757.

Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands

N. C. Bruno and Buchwald, S. L. “Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands”, Org. Lett., 2013, 15(11), 2876 - 2879.

N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings

N. C. Bruno, Niljianskul, N. , and Buchwald, S. L. “N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings”, J. Org. Chem., 2014, 79(9), 4161 - 4166.

Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation

X. Wang and Buchwald, S. L. “Synthesis of Optically Pure 2-Trifluoromethyl Lactic Acid by Asymmetric Hydroformylation”, J. Org. Chem., 2013, 78(7), 3429 - 3433.

Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents

Y. Zhu and Buchwald, S. L. “Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents”, J. Am. Chem. Soc., 2014, 136(12), 4500 - 4503.

Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation

A. M. Düfert, Billingsley, K. L. , and Buchwald, S. L. “Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation”, J. Am. Chem. Soc., 2013, 135(34), 12877 - 12885.

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

Y. Yang and Buchwald, S. L. “Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides”, J. Am. Chem. Soc., 2013, 135(29), 10642 - 10645.

Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids

R. J. DeBergh, Niljianskul, N. , and Buchwald, S. L. “Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids”, J. Am. Chem. Soc., 2013, 135(29), 10638 - 10641.

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