C—C (All)

Carbon—carbon bond forming reactions.

An integrated microreactor system for self-optimization of a Heck reaction: from micro- to mesoscale flow systems

J. P. McMullen, Stone, M. T. , Buchwald, S. L. , and Jensen, K. F. “An integrated microreactor system for self-optimization of a Heck reaction: from micro- to mesoscale flow systems”, Angew. Chem. Int. Ed., 2010, 49(39), 7076-7080.

Multistep microchemical synthesis enabled by microfluidic distillation

R. L. Hartman, Naber, J. R. , Buchwald, S. L. , and Jensen, K. F. “Multistep microchemical synthesis enabled by microfluidic distillation”, Angew. Chem. Int. Ed., 2010, 49(5), 899-903.

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

R. Martin and Buchwald, S. L. “Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands”, Acc. Chem. Res., 2008, 41(11), 1461-1473.

An extremely active catalyst for the Negishi cross-coupling reaction

J. E. Milne and Buchwald, S. L. “An extremely active catalyst for the Negishi cross-coupling reaction”, J. Am. Chem. Soc., 2004, 126(40), 13028-32.

A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: novel ligand coordination

J. Yin, Rainka, M. P. , Zhang, X. X. , and Buchwald, S. L. “A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: novel ligand coordination”, J. Am. Chem. Soc., 2002, 124(7), 1162-3.

A Highly Active Catalyst for the Room-Temperature Amination and Suzuki Coupling of Aryl Chlorides

J. P. Wolfe and Buchwald, S. L. “A Highly Active Catalyst for the Room-Temperature Amination and Suzuki Coupling of Aryl Chlorides”, Angew. Chem. Int. Ed., 1999, 38(16), 2413-2416.

A phosphane-free catalyst system for the Heck arylation of disubstituted alkenes: Application to the synthesis of trisubstituted olefins

C. Gurtler and Buchwald, S. L. “A phosphane-free catalyst system for the Heck arylation of disubstituted alkenes: Application to the synthesis of trisubstituted olefins”, Chem. Eur. J., 1999, 5, 3107-3112.

Carbonylation of Aryl Chlorides with Oxygen Nucleophiles at Atmospheric Pressure. Preparation of Phenyl Esters as Acyl Transfer Agents and the Direct Preparation of Alkyl Esters and Carboxylic Acids

D. A. Watson, Fan, X. , and Buchwald, S. L. “Carbonylation of Aryl Chlorides with Oxygen Nucleophiles at Atmospheric Pressure. Preparation of Phenyl Esters as Acyl Transfer Agents and the Direct Preparation of Alkyl Esters and Carboxylic Acids”, J. Org. Chem., 2008, 73(18), 7096-7101.

Palladium-Catalyzed Stille Cross-Coupling Reaction of Aryl Chlorides using a Pre-Milled Palladium Acetate and XPhos Catalyst System

J. R. Naber and Buchwald, S. L. “Palladium-Catalyzed Stille Cross-Coupling Reaction of Aryl Chlorides using a Pre-Milled Palladium Acetate and XPhos Catalyst System”, Adv. Synth. Cat., 2008, 350(7-8), 957-961.

Palladium-Catalyzed Carbonylation of Aryl Tosylates and Mesylates

R. H. Munday, Martinelli, J. R. , and Buchwald, S. L. “Palladium-Catalyzed Carbonylation of Aryl Tosylates and Mesylates”, J. Am. Chem. Soc., 2008, 130(9), 2754-2755.

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