C—C (All)

Carbon—carbon bond forming reactions.

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct

R. Y. Liu, Zhou, Y. , Yang, Y. , and Buchwald, S. L. “Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct”, J. Am. Chem. Soc., 2019, 141, 2251-2256.

Copper-Catalyzed Enantioselective Hydroamination of Alkenes

R. Y. Liu and Buchwald, S. L. “Copper-Catalyzed Enantioselective Hydroamination of Alkenes”, Org. Syn., 2018, 95, 80-96.

Asymmetric Cu-Catalyzed 1,4-Dearomatization of Pyridines and Pyridazines without Preactivation of the Heterocycle or Nucleophile

M. W. Gribble, Guo, S. , and Buchwald, S. L. “Asymmetric Cu-Catalyzed 1,4-Dearomatization of Pyridines and Pyridazines without Preactivation of the Heterocycle or Nucleophile”, J. Am. Chem. Soc., 2018, 140(15), 5057-5060.

A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes

E. Tsai, Liu, R. Y. , Yang, Y. , and Buchwald, S. L. “A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes”, J. Am. Chem. Soc, 2018, 140, 2007-2011.

Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates

Y. Zhou, Bandar, J. S. , and Buchwald, S. L. “Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates”, J. Am. Chem. Soc, 2017, 139(24), 8126–8129.

A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl–Aryl Cross-Coupling of Aryl Halides and Olefins

S. D. Friis, Pirnot, M. T. , Dupuis, L. N. , and Buchwald, S. L. “A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl–Aryl Cross-Coupling of Aryl Halides and Olefins”, Angew. Chem. Int. Ed., 2017, 56(25), 7242–7246 .

Direct 11CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions

W. Zhao, Lee, H. Geun, Buchwald, S. L. , and Hooker, J. M. “Direct 11CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions”, J. Am. Chem. Soc, 2017, 139(21), 7152–7155.

Suzuki-Miyaura cross-coupling optimization enabled by automated feedback

B. J. Reizman, Wang, Y. - M. , Buchwald, S. L. , and Jensen, K. F. “Suzuki-Miyaura cross-coupling optimization enabled by automated feedback”, Reaction Chemistry & Engineering, 2016, 1, 658-666 .

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes

R. Y. Liu, Yang, Y. , and Buchwald, S. L. “Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes”, Angew. Chem. Int. Ed., 2016, 55(45), 14077-14080.

Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration

Y. Yang, Perry, I. B. , and Buchwald, S. L. “Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration”, J. Am. Chem. Soc., 2016, 138(31), 9787-9790.

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