C—C (All)

Carbon—carbon bond forming reactions.

Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles

J. Levi Knippel, Ye, Y. , and Buchwald, S. L. “Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles”, Org. Lett., 2021, 23, 2153-2157.

Palladium–Protein Oxidative Addition Complexes by Amine-Selective Acylation

H. H. Dhanjee, Buslov, I. , Windsor, I. W. , Raines, R. T. , Pentelute, B. L. , and Buchwald, S. L. “Palladium–Protein Oxidative Addition Complexes by Amine-Selective Acylation”, J. Am. Chem. Soc., 2020, 142(51), 21237 - 21242.

Evidence for Simultaneous Dearomatization of Two Aromatic Rings Under Mild Conditions in Cu(I)-Catalyzed Direct Asymmetric Dearomatization of Pyridine

M. W. Gribble, Liu, R. Y. , and Buchwald, S. L. “Evidence for Simultaneous Dearomatization of Two Aromatic Rings Under Mild Conditions in Cu(I)-Catalyzed Direct Asymmetric Dearomatization of Pyridine”, J. Am. Chem. Soc., 2020, 142(25), 11252-11269.

The Enantioselective Preparation of Arenes with β-Stereogenic Centers: Confronting the 1,1-Disubstituted Olefin Problem Using CuH/Pd Cooperative Catalysis

Z. Lu and Buchwald, S. L. “The Enantioselective Preparation of Arenes with β-Stereogenic Centers: Confronting the 1,1-Disubstituted Olefin Problem Using CuH/Pd Cooperative Catalysis”, Angew. Chem. Int. Ed., 2020, https://doi.org/10.1002/anie.202004414.

Highly Enantioselective Synthesis of Indazoles with a C3-Quaternary Chiral Center Using CuH Catalysis

Y. Ye, Kevlishvili, I. , Feng, S. , Liu, P. , and Buchwald, S. L. “Highly Enantioselective Synthesis of Indazoles with a C3-Quaternary Chiral Center Using CuH Catalysis”, J. Am. Chem. Soc., 2020, 142(23), 10550-10556.

Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles

Y. Zhou, Zhou, L. , Jesikiewicz, L. T. , Liu, P. , and Buchwald, S. L. “Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles”, J. Am. Chem. Soc., 2020, 142(22), 9908-9914.

Enantioselective Olefin Hydrocyanation Without Cyanide

A. W. Schuppe, Borrajo-Calleja, G. M. , and Buchwald, S. L. “Enantioselective Olefin Hydrocyanation Without Cyanide”, J. Am. Chem. Soc., 2019, 141, 18668-18672.

Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles

C. Li*, Shin*, K. , Y.Liu, R. , and Buchwald, S. L. “Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles”, Angew. Chem. Int. Ed., 2019, 58, 17074-17080.

CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications

C. Li, Liu, R. Y. , Jesikiewicz, L. T. , Yang, Y. , Liu, P. , and Buchwald, S. L. “CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications”, J. Am. Chem. Soc., 2019, 141(12), 5062-5070.

CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence

Y. Ye, Kim, S. - T. , Jeong, J. , Baik, M. - H. , and Buchwald, S. L. “CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence”, J. Am. Chem. Soc., 2019, 141(9), 3901-3909.

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